General Characteristics of Alloy Steel 4340

4340 is a nickel-chromium-molybdenum alloy steel known for its toughness and its ability to attain high strengths in the heat-treated condition. It has very good fatigue resistance.


Chemical Analysis

Carbon 0.38 – 0.43
Chromium 0.7 – 0.9
Iron Balance
Manganese 0.6 – 0.8
Molybdenum 0.2 – 0.3
Nickel 1.65 – 2
Phosphorus 0.035 max
Silicon 0.15 – 0.3
Sulphur 0.04 max




Commercial and military aircraft, automotive systems, forged hydraulic and other machine tool applications, forged steel crankshafts.



Forging should be carried out between 2250 and 1800ºF (1230 and 980 degrees C). Parts should be slow cooled after forging in ashes or sand etc.


Heat Treatment

Heat treatment after forging is carried out to render the steel suitable for machining, and to meet the mechanical property limits specified for the steel’s particular applications. There are several ways to heat treat a given steel part and it is only through practice that the optimum treatments, temperatures and conditions may be defined. The following information should be taken as a guide only.


To obtain a pearlitic structure on certain parts for machining, 4340 should be annealed at a nominal temperature of 1525º F (830ºC,) cooling to 1350ºF (730ºC) and furnace cooling to 1130º F (610ºC) at a rate of 20ºF (11ºC) per hour, then air cooling. This process, known as full annealing, is very time consuming as it involves slow cooling over the entire temperature range from the austenitizing temperature to a temperature well below that at which transformation is complete. To obtain a spheroidized structure in 4340 grade involves austenitizing at 1380 o F (750ºC,) furnace cooling to 1300 o F (705ºC) then to 1050ºF (565º C) at a rate of 5ºF (3ºC) per hour. This structure will probably result in better machinability than will the coarse lamellar pearlite structure obtained by the full anneal process.


This process is defined as heating a steel to a temperature above the ferrite to austenite transformation temperature, then cooling in air to a temperature well below this transformation temperature. The treatment may be carried out on forged products as a conditioning treatment prior to final heat treatment. Normalizing also serves to refine the structure of forgings that might have cooled non-uniformly from their forging operation. The nominal normalizing temperature for 4340 grade is 1500ºF (815ºC,) but production experience may necessitate a temperature either 50º F (10º C) above or below this temperature. . As a rule of thumb, when forgings are normalized before, say, carburizing or hardening and tempering, the upper range of normalizing temperatures is used. When normalizing is the final heat treatment, the lower temperature range is used.


This heat treatment results in the formation of martensite after quenching, resulting in increased hardness and tensile strength. A temperature range of 1500 – 1550º  F (815 – 845ºC) is the normal austenitizing temperature for direct hardening of 4340 grade. Oil quenching is normally used for 4340 as the alloy’s hardenability is suited to this quenching method.


Tempering is carried out to relieve stresses from the hardening process, but primarily to obtain mechanical properties required for the final application. The actual tempering temperature will be chosen to meet the required properties, and in many cases will be a matter of trial and error. This alloy steel should not be tempered between 400-790 o F (200-420 o C) to prevent embrittlement

This grade may also be hardened by nitriding or flame or induction hardening.


This grade is readily machinable, with either a coarse lamellar pearlitic structure or a spheroidized structure being best advised, depending upon section size and complexity and amount of machining to be carried out. If there is doubt about the suitability of any other structure, then a spheroidizrd structure should be aimed for in heat treatment.


This grade is readily welded in the annealed condition, but welding in the hardened and tempered condition should be avoided where possible because of the effect on mechanical properties. Welding in the nitrided or flame or induction hardened conditions is not recommended.

Guidance details for welding include the use of low-hydrogen electrodes and a preheat from 400 –

570ºF (200 – 300º C,) if possible to be maintained during welding. Parts should be slow cooled after

Welding in ashes or sand and stress relieved if possible.


This alloy, 4340, may be heat treated to high strength levels while maintaining

good toughness, wear resistance and fatigue strength levels, combined with good atmospheric corrosion resistance, and strength up to around 600º F (315º C.)